CEE Kerala Engineering CEE Kerala Engineering Solved Paper-2001

  • question_answer
    The pair of \[[PtC{{l}_{2}}{{(N{{H}_{3}})}_{4}}]B{{r}_{2}}\]and \[[PtB{{r}_{2}}{{(N{{H}_{3}})}_{4}}]C{{l}_{2}}\]constitutes a pair of:

    A) co-ordination isomers

    B) linkage isomers

    C) ionization isomers

    D) hydrate isomers

    E) optical isomers

    Correct Answer: C

    Solution :

    \[[PtC{{l}_{2}}{{(N{{H}_{3}})}_{4}}]B{{r}_{2}}\]and\[[PtB{{r}_{2}}{{(N{{H}_{3}})}_{4}}]C{{l}_{2}}\]shows ionization isomerism because in ionization isomerism the difference arises from the position of groups within or outside the co-ordination sphere. Therefore, these isomers give different ions in the solution.


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