CEE Kerala Engineering CEE Kerala Engineering Solved Paper-2010

  • question_answer
    Hyperconjugation is most useful for stabilising which of the following carbocations?

    A)  Neo-pentyl      

    B)  Tert-butyl

    C) \[Iso-\]propyl       

    D)         Ethyl

    E)  Methyl

    Correct Answer: B

    Solution :

    On the basis of hyperconjugation, stability order of different alkyl carbocations is \[3{}^\circ >2{}^\circ >1{}^\circ >methyl\] In t-butyl cation, the C-atom bearing the positive charge is attached to three methyl groups, thus it will have maximum hyperconjugative structures, which give it maximum stability.


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