CET Karnataka Medical CET - Karnataka Medical Solved Paper-2001

  • question_answer
    For the reaction \[{{H}_{2}}O(s)\rightleftharpoons {{H}_{2}}O(l)\] at \[{{0}^{o}}C\]and normal pressure:

    A)  \[\Delta H>T\Delta S\]

    B)  \[\Delta H=T\Delta S\]

    C)  \[\Delta H=\Delta G\]

    D)  \[\Delta H<T\Delta S\]

    Correct Answer: B

    Solution :

    \[{{H}_{2}}O(g)\rightleftharpoons {{H}_{2}}O(l)\] We know that \[\Delta G=\Delta H-T\Delta S\] At equilibrium \[\Delta G=0\] Therefore  \[\Delta H=T\Delta S\]


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