CET Karnataka Medical CET - Karnataka Medical Solved Paper-2005

  • question_answer
    Molar heat of vaporisation of a liquid is \[6kj\,mo{{l}^{-1}}\] . If the entropy change is \[16J\,mo{{l}^{-1}}{{K}^{-1}}\] , the boiling point of the liquid is :

    A)  \[{{375}^{o}}C\]

    B)  \[375K\]

    C)  \[273K\]

    D)  \[{{102}^{o}}C\]

    Correct Answer: B

    Solution :

    \[\Delta S=16J\,mo{{l}^{-1}}\,{{K}^{-1}},\,\Delta {{H}_{p}}=6kJ\,mo{{l}^{-1}}\] \[{{T}_{b.p.}}=\frac{\Delta {{H}_{vapour}}}{\Delta {{S}_{vapour}}}=\frac{6\times 1000}{16}=375K\]


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