CET Karnataka Medical CET - Karnataka Medical Solved Paper-2007

  • question_answer
    The number of antibonding electron pairs in \[O_{2}^{2-}\]molecular ion on the basis of molecular orbital theory is (Atomic number of 0 is 18.)

    A)  \[5\]              

    B)  \[4\]

    C)  \[3\]             

    D)  \[2\]

    Correct Answer: B

    Solution :

    The electronic configuration of \[O_{2}^{2-}\] ion is \[O_{2}^{2-}-\sigma 1{{s}^{2}},\overset{*}{\mathop{\sigma }}\,1{{s}^{2}},\sigma 2{{s}^{2}},\overset{*}{\mathop{\sigma }}\,2{{s}^{2}},\sigma 2p_{z}^{2},\pi 2p_{x}^{2},\] \[\pi 2p_{y}^{2},\overset{*}{\mathop{\pi }}\,2p_{x}^{2}.\overset{*}{\mathop{\pi }}\,2p_{y}^{2}\] Hence, number of antibonding electron pairs in \[O_{2}^{2-}\] molecular ion are four.


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