A) Favoured by polar solvents
B) \[{{3}^{o}}\]-alkyl halides generally react through \[{{S}_{N}}1\] reaction.
C) The rate of the reaction does not depend upo the molar concentration of the nucleophile.
D) \[{{1}^{o}}\]-alkyl halides generally react through \[{{S}_{N}}1\]reaction.
Correct Answer: D
Solution :
: \[{{S}_{N}}1\] reaction is favoured by bulky groups on the carbon atom attached to halogens; i.e., the order of reactivity is \[\underset{Tertiary}{\mathop{{{R}_{3}}C-X}}\,>\underset{Secondary}{\mathop{{{R}_{2}}CH-X}}\,>\underset{\text{Primary}}{\mathop{RC{{H}_{2}}-X}}\,>\underset{Methyl}{\mathop{C{{H}_{3}}-X}}\,\]
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