CET Karnataka Medical CET - Karnataka Medical Solved Paper-2013

  • question_answer
    The reagent used to distinguish between acetaldehyde and Benz aldehyde is

    A)  Tollens reagent

    B)  Fehlings solution

    C)  2, 4-dinitrophenylhydrazine

    D)  semicarbazide

    Correct Answer: B

    Solution :

    :  \[\underset{\begin{smallmatrix}  Aliphatic \\  aldehyde \end{smallmatrix}}{\mathop{R-CHO}}\,+\underbrace{2C{{u}^{2+}}+5O{{H}^{-}}}_{Fehling\,solution}\xrightarrow{\Delta }\]\[\underset{\begin{smallmatrix}  Cuprous\,oxide \\  \text{(Red}\,\text{ppt}\text{.)} \end{smallmatrix}}{\mathop{RCO{{O}^{-}}+C{{u}_{2}}O\downarrow +3{{H}_{2}}O}}\,\] Benzaldehyde does not respond to Fehlings solution due to alkaline nature of this reagent


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