CET Karnataka Medical CET - Karnataka Medical Solved Paper-2015

  • question_answer
    On heating with concentrated \[NaOH\] solution in an inert atmosphere of \[C{{O}_{2}}\], white phosphorus gives a gas. Which of the following statements is incorrect about the gas?

    A)  It is more basic than \[N{{H}_{3}}\]

    B)  Its solution in water decomposes in the presence of light.

    C)  It is less basic than \[N{{H}_{3}}\].

    D)  It is highly poisonous and has smell like rotten fish.

    Correct Answer: A

    Solution :

    : \[{{P}_{4}}+3NaOH+3{{H}_{2}}O\xrightarrow[C{{O}_{2}}]{\Delta }3Na{{H}_{2}}P{{O}_{2}}+\underset{Phosphine}{\mathop{P{{H}_{3}}\uparrow }}\,\] \[P{{H}_{3}}\] is less basic than \[N{{H}_{3}}\] as the electron density is diffused over the larger phosphorus atom.


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