CMC Medical CMC-Medical Ludhiana Solved Paper-2007

  • question_answer
    Which of the following on heating does not form an anhydride?

    A)  Oxalic acid         

    B)  Succinic acid

    C)  Glutaric acid     

    D)  Maleic acid

    Correct Answer: A

    Solution :

                    Since, three-membered rings are quite unstable, therefore, oxalic acid on heating does not form an anhydride. Instead it decomposes to give \[C{{O}_{2}}+CO+{{H}_{2}}O\] \[\underset{COOH}{\overset{COOH}{\mathop{|}}}\,\xrightarrow{\Delta }C{{O}_{2}}+\underset{CO\,\,+\,\,{{H}_{2}}O}{\mathop{\underset{\downarrow \Delta }{\mathop{[HCOOH]}}\,}}\,\]


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