CMC Medical CMC-Medical VELLORE Solved Paper-2007

  • question_answer
    The right order of the solubility of sulphates of alkaline earth metals in water is

    A)  Be > Ca > Mg > Ba > Sr

    B)  Mg > Be > Ba > Ca > Sr

    C)  Be > Mg > Ca > Sr > Ba

    D)  Mg > Ca > Ba > Be > Sr

    Correct Answer: C

    Solution :

                    Be > Mg > Ca > Sr > Ba. The size of the \[SO_{4}^{2-}\]ion is very big (approx. 3\[\overset{\text{o}}{\mathop{\text{A}}}\,\]). Therefore, as the size of the cation increases, their hydration energies decrease more rapidly than their lattice energies. Consequently the solubilities of sulphates decrease down the group.


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