DUMET Medical DUMET Medical Solved Paper-2001

  • question_answer
    When primary alcohol is oxidized with chlorine, it gives:

    A)  \[C{{l}_{3}}HO\]     

    B)  \[C{{H}_{3}}CHO\]

    C)  \[CC{{l}_{3}}CHO\]   

    D)  \[C{{H}_{3}}COC{{H}_{3}}\]

    Correct Answer: C

    Solution :

    \[C{{H}_{3}}C{{H}_{2}}OH\xrightarrow[-2HCl]{C{{l}_{2}}}C{{H}_{3}}CHO\] \[\xrightarrow[-3HCl]{3C{{l}_{2}}}\underset{chloral}{\mathop{CC{{l}_{3}}CHO}}\,\]


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