DUMET Medical DUMET Medical Solved Paper-2001

  • question_answer
    Arrange the following in order of increasing C - C bond length?  
    (i) \[{{C}_{6}}{{H}_{6}}\]
    (ii) \[CH\equiv CH\]
    (iii) \[{{H}_{3}}C-C{{H}_{3}}\]
    (iv) \[{{H}_{2}}C-C{{H}_{2}}\]
     

    A)  \[I>II>III>IV\]

    B)  \[II>IV>I>III\]

    C)  \[III>I>IV>II\]

    D)  \[III>IV>II>I\]

    Correct Answer: B

    Solution :

    C?C bond length in \[{{C}_{6}}{{H}_{6}}\] is \[1.39\,\overset{o}{\mathop{A}}\,\], \[HC\equiv CH\] is \[1.20\,\overset{o}{\mathop{A}}\,\], \[{{H}_{3}}C-C{{H}_{3}}\] is \[1.54\,\overset{o}{\mathop{A}}\,\], \[{{H}_{2}}C=C{{H}_{2}}\] is \[1.34\,\overset{o}{\mathop{A}}\,\]. \[\therefore \] The correct order is \[HC\equiv CH<{{H}_{2}}C=C{{H}_{2}}<{{C}_{6}}{{H}_{6}}<{{H}_{3}}C-C{{H}_{3}}\] \[II<IV<I<III\]


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