DUMET Medical DUMET Medical Solved Paper-2003

  • question_answer
    Isocyanide can be prepared from alkyl halide on treatment with:

    A)  KNC         

    B)  AgNC

    C)  KCN          

    D)  AgCN

    Correct Answer: D

    Solution :

    Key Idea: Alkyl cyanide is prepared by reaction between alkyl halide KCN but alkyl halide on reaction with \[AgCN\] form alkyl isocyanide. \[\underset{alkyl\text{ }halide}{\mathop{R\,\,X\,\,+}}\,\,\,\,\,\underset{silver\text{ }cyanide}{\mathop{AgCN\to }}\,\,\,\,\underset{iso-cyanida}{\mathop{R\overset{\to }{\mathop{=}}\,NC+}}\,Ag\,X\]


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