DUMET Medical DUMET Medical Solved Paper-2003

  • question_answer
    What is obtained, when acetic acid is heated with chlorine in presence of red phosphorus?

    A)  Acetyl chloride

    B)  \[\alpha \]-chloro acetic acid

    C)  Acetic anhydride

    D)  Chloral

    Correct Answer: B

    Solution :

    Key Idea: In presence of red phosphorus, acids having a-hydrogen atom give a-substituted acids. This reaction is called Hell-Vollhard Zeiinsky \[(HVZ)\] reaction. \[C{{H}_{3}}COOH+C{{l}_{2}}\xrightarrow{\operatorname{Re}d\,P}\,\,\underset{\alpha \,\,-chloro\text{ }acetic\text{ }acid}{\mathop{\overset{\begin{smallmatrix}  Cl \\  | \end{smallmatrix}}{\mathop{C}}\,{{H}_{2}}COOH}}\,\]


You need to login to perform this action.
You will be redirected in 3 sec spinner