DUMET Medical DUMET Medical Solved Paper-2003

  • question_answer
    What is the EAN of nickel in \[Ni{{(CO)}_{4}}\]?

    A)  34           

    B)  35

    C)  32            

    D)  36

    Correct Answer: D

    Solution :

    Key Idea: EAN = Ac. no. of central metal atom oxidation state of central metal atom + electrons gained from ligands Atomic no. of Ni = 28 Oxidation state of Ni in \[[Ni{{(CO)}_{4}}]=0\] (\[\because \] Oxidation state of metal in carbonyl is zero) Electrons gained from ligands \[=2\times 4=8\] (\[\because \] One ligand donates two electrons to metal atom.) \[\therefore \] \[EAN=28-0+8=36\]


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