DUMET Medical DUMET Medical Solved Paper-2009

  • question_answer
    The expected spin-only magnetic moments for \[{{[Fe{{(CN)}_{6}}]}^{4-}}\] and \[{{[Fe{{F}_{6}}]}^{3-}}\] are

    A)  1.73 and 1.73 BM

    B)  1.73 and 5.92 BM

    C)  0.0 and 1.73 BM

    D)  0.0 and 5.92 BM

    Correct Answer: D

    Solution :

    \[\because \] No. of unpaired electrons in [Fe(CN)6]4 = 0 \[\therefore \] Spin-only magnetic moment \[=\sqrt{n(n+2)}BM\]= 0 Again, no. of unpaired electrons in \[{{[Fe{{F}_{6}}]}^{3-}}=5\] \[\therefore \] Spin-only magnetic moment \[=\sqrt{n(n+2)}BM\] \[=\sqrt{5(5+2)}BM\] \[=\sqrt{35}BM\] = 5.916 BM


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