DUMET Medical DUMET Medical Solved Paper-2009

  • question_answer
    Which of the following reactions will not give the anhydrous\[AlC{{l}_{3}}\]?

    A)  By heating \[AlC{{l}_{3}}\,\,6{{H}_{2}}O\]

    B)  By passing dry \[HCl\] gas on heated aluminium powder

    C)  By passing dry chlorine gas on heated aluminium powder

    D)  By passing dry chlorine gas over a heated mixture of alumina and coke

    Correct Answer: A

    Solution :

    [a] \[2AlC{{l}_{3}}6{{H}_{2}}O\xrightarrow{\Delta }A{{l}_{2}}{{O}_{3}}+6HCl\uparrow \] \[+9{{H}_{2}}O\uparrow \] [b] \[2Al+\underset{(dry)}{\mathop{3HCl}}\,\xrightarrow{{}}2AlC{{l}_{3}}+3{{H}_{2}}\uparrow \] [c] \[2Al+\underset{(dry)}{\mathop{3C{{l}_{2}}}}\,\xrightarrow{{}}2AlC{{l}_{3}}\] [d] \[A{{l}_{2}}{{O}_{3}}+3C+3C{{l}_{2}}\xrightarrow{{}}2AlC{{l}_{3}}+3CO\uparrow \]


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