DUMET Medical DUMET Medical Solved Paper-2011

  • question_answer
    More acidic than ethanol is

    A)  \[C{{H}_{3}}C{{H}_{2}}C{{H}_{2}}C{{H}_{2}}C{{H}_{2}}C{{H}_{2}}C{{H}_{2}}C{{H}_{3}}\]

    B)  \[C{{H}_{3}}C{{O}_{2}}C{{H}_{2}}C{{H}_{3}}\]

    C)  \[C{{H}_{3}}COC{{H}_{2}}COC{{H}_{3}}\]

    D)  \[C{{H}_{3}}COC{{H}_{3}}\]

    Correct Answer: C

    Solution :

    Pentane-2, 4-dione is more acidic than ethanol, because it is an active methylene compound and after the emission of proton, the anion is resonance stabilized.    \[C{{H}_{3}}-\overset{\begin{smallmatrix}  O \\  || \end{smallmatrix}}{\mathop{C}}\,-CH=\overset{\begin{smallmatrix}  {{O}^{-}} \\  | \end{smallmatrix}}{\mathop{C}}\,-C{{H}_{3}}\]


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