EAMCET Medical EAMCET Medical Solved Paper-2004

  • question_answer
    The  product  formed   in  the  aldol condensation of acetaldehyde:

    A)  \[C{{H}_{3}}C{{H}_{2}}CH(OH)CHO\]

    B)  \[C{{H}_{3}}CH(OH)C{{H}_{2}}CHO\]

    C)  \[C{{H}_{3}}CH(OH)COC{{H}_{2}}\]

    D)  \[C{{H}_{3}}C{{H}_{2}}C{{H}_{2}}CHO\]

    Correct Answer: B

    Solution :

                     Aldol   condensation   :   Aldehydes containing  \[\alpha -\]hydrogen  undergo  self addition in presence of a base to form products called aldols. The reaction is called aldol.  condensation. Example: Two molecules of acetaldehyde combine with each other in presence of dil. NaOH to form 3 -hydroxybutanal. \[C{{H}_{3}}CHO+HC{{H}_{2}}CHO\xrightarrow{O{{H}^{-}}}\] \[\underset{3}{\mathop{C{{H}_{3}}}}\,-\underset{\text{hydroxybutanal}}{\mathop{\overset{OH}{\mathop{\overset{|}{\mathop{CH}}\,}}\,-C{{H}_{2}}}}\,-\underset{(aldol)}{\mathop{CHO}}\,\]


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