EAMCET Medical EAMCET Medical Solved Paper-2004

  • question_answer
    Which one of the following compounds decolourises   cold   alkaline   potassium permanganate solution?

    A)  \[{{C}_{2}}{{H}_{6}}\]                   

    B)  \[{{C}_{2}}{{H}_{5}}Cl\]

    C)  \[{{C}_{2}}{{H}_{4}}\]                   

    D)  \[{{C}_{2}}{{H}_{5}}OC{{H}_{3}}\]

    Correct Answer: C

    Solution :

                     Cold alkaline potassium permanganate solution (1% alkaline \[\text{KMn}{{\text{O}}_{\text{4}}}\]or Baeyers reagent) is decolourised in presence of unsaturation only. In the given compounds only ethylene is unsaturated compound. So, it decolourise Baeyers reagent as : \[2KMn{{O}_{4}}2KOH\xrightarrow{{}}2{{K}_{2}}Mn{{O}_{4}}+\underbrace{{{H}_{2}}O+[O]}_{{}}\] \[\underset{\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,C{{H}_{2}}OH}{\mathop{\underset{|}{\mathop{C}}\,}}\,{{H}_{2}}OH\] Ethylene glycol (Colourless)


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