EAMCET Medical EAMCET Medical Solved Paper-2005

  • question_answer
    Consider the following reaction : \[{{C}_{2}}{{H}_{5}}OK+{{C}_{2}}{{H}_{5}}I\xrightarrow{\Delta }X\,(pleasant\,smelling\,liquid)\]  Which of the following reagents converts  ethylbromide to X ?

    A)  Sodium                               

    B)  Dry silver oxide

    C)  Ethyl chloride   

    D)  Dry silver powder

    Correct Answer: B

    Solution :

                     \[{{C}_{2}}{{H}_{5}}OK+{{C}_{2}}{{H}_{5}}I\xrightarrow{\Delta }\underset{\text{diethyl}\,\text{ether}}{\mathop{{{C}_{2}}{{H}_{5}}O{{C}_{2}}{{H}_{5}}}}\,+KI\] This is Williamsons synthesis of ether. Ether can also be prepared by the action of dry silver oxide on ethyl bromide. \[2{{C}_{2}}{{H}_{5}}Br+A{{g}_{2}}O\xrightarrow{\Delta }{{C}_{2}}{{H}_{5}}O{{C}_{2}}{{H}_{5}}\]\[+2AgBr\]


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