EAMCET Medical EAMCET Medical Solved Paper-2009

  • question_answer
    Which one of the following statements is not true for glucose?

    A)  \[\alpha -D(+)-\]glucose undergoes mutarotation

    B)  It has four asymmetric carbons is Fischer projection formula

    C)  It gives saccharic acid with Tollens reagent

    D)  It reacts with hydroxyl amine

    Correct Answer: C

    Solution :

                     Glucose reduces Tollens reagent and gets oxidised into gluconic acid. \[\underset{C{{H}_{2}}OH}{\overset{CHO}{\mathop{\underset{|}{\overset{|}{\mathop{(CHOH)}}}\,}}}\,+A{{g}_{2}}O\xrightarrow{{}}\underset{\begin{smallmatrix}  C{{H}_{2}}OH \\  gluconic\,acid \end{smallmatrix}}{\overset{COOH}{\mathop{\underset{|}{\overset{|}{\mathop{{{(CHOH)}_{4}}}}}\,}}}\,+\underset{\begin{smallmatrix}  \text{silver} \\  \text{mirror} \end{smallmatrix}}{\mathop{2Ag}}\,\]


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