EAMCET Medical EAMCET Medical Solved Paper-2010

  • question_answer
    Which one of the following compounds is formed when nitrobenzene is treated with bromine in the presence of ferric ion?

    A)  m-bromonitrobenzene

    B)  o-bromonitrobenzene

    C)  p-bromonitrobenzene

    D)  Mixture of o - and p -bromonitrobenzene

    Correct Answer: A

    Solution :

    \[-\text{N}{{\text{O}}_{\text{2}}}\]group being electron withdrawing decreases the electron density at ortho/para position. Thus, now electrophile attacks at meta position as it is electron rich as compared to ortho/para positions. \[B{{r}_{2}}+F{{e}^{3+}}\xrightarrow[{}]{{}}F{{e}^{3+}}+\underset{\text{electrophile}}{\mathop{B{{r}^{+}}}}\,\]


You need to login to perform this action.
You will be redirected in 3 sec spinner