EAMCET Medical EAMCET Medical Solved Paper-2010

  • question_answer
    The oxidation numbers of sulphur in \[{{\text{S}}_{\text{8}}}\text{,S}{{\text{O}}_{\text{2}}}\]and \[{{\text{H}}_{\text{2}}}\text{S,}\]respectively are

    A)  \[~0,+6,-2\]                      

    B)  \[0,+4,-2\]

    C)  \[0,+1,+2\]                        

    D)  \[0,+1,-2\]

    Correct Answer: B

    Solution :

                     The oxidation state of an element in its free state is zero, ie, oxidation state of S in \[{{\text{S}}_{\text{8}}}\]is O. Let the oxidation state of S in \[\text{S}{{\text{O}}_{2}}\]and \[{{\text{H}}_{\text{2}}}\text{O}\]is \[x\]. \[\underset{\begin{smallmatrix}  x+(-2)\,\times \,2\,=\,0 \\  \,\,\,\,\,\,\,\,\,\,\,x-4=0  \\  \,\,\,\,\,\,\,\,\,\,x=+\,4 \end{smallmatrix}}{\mathop{S{{O}_{2}}}}\,\]                     \[\underset{\begin{smallmatrix}  (1)\,\times \,2+x=0 \\  \,\,\,\,\,\,\,\,\,\,\,\,2+x=0  \\  \,\,\,\,\,\,\,\,\,\,x=-2 \end{smallmatrix}}{\mathop{{{H}_{2}}S}}\,\] Thus, the oxidation states of S, in \[{{\text{S}}_{\text{8}}}\text{,S}{{\text{O}}_{\text{2}}}\]and \[{{\text{H}}_{\text{2}}}\text{S}\]are respectively 0, + 4 and - 2.


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