J & K CET Engineering J and K - CET Engineering Solved Paper-2003

  • question_answer
    Reaction of t-butyl bromide with sodium methoxide produces

    A)  isobutane

    B)  isobutylene

    C)  sodium-t-butoxide

    D)  t-butylmethylether

    Correct Answer: B

    Solution :

     \[\underset{t-\text{butylbromide}}{\mathop{C{{H}_{3}}-\underset{C{{H}_{3}}}{\overset{C{{H}_{3}}}{\mathop{\underset{|}{\overset{|}{\mathop{C}}}\,}}}\,-Br}}\,+\underset{\begin{smallmatrix}  \,\,\,\,\text{sodium} \\  \text{methoxide} \end{smallmatrix}}{\mathop{C{{H}_{3}}ONa}}\,\to \underset{\begin{smallmatrix}  2-\text{methyl}\,\text{propene} \\  \,\,\,\,\,\,\,\,\,(isobutylene) \end{smallmatrix}}{\mathop{C{{H}_{3}}-\overset{C{{H}_{3}}}{\mathop{\overset{|}{\mathop{C}}\,}}\,=C{{H}_{2}}}}\,\] \[\underset{\text{methanol}}{\mathop{+\,C{{H}_{3}}OH}}\,+NaBr\]


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