J & K CET Engineering J and K - CET Engineering Solved Paper-2006

  • question_answer
    The correct order for homolytic bond dissociation energies (\[\Delta H\]in kcal/mol) for \[C{{H}_{4}}(A),{{C}_{2}}{{H}_{6}}(B)\]and\[C{{H}_{3}}Br(C),\]under  identical experimental conditions

    A) \[C>B>A\]    

    B) \[B>C>A\]

    C) \[~C>A>B\]    

    D) \[~A>B>C\]

    Correct Answer: D

    Solution :

     The order of homolytic bond dissociation energies of \[C{{H}_{4}},{{C}_{2}}{{H}_{6}}\]and \[C{{H}_{3}}Br\]is as \[\begin{align}   & \,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,C{{H}_{4}}>{{C}_{2}}{{H}_{6}}>C{{H}_{3}}Br \\  & \Delta \Eta (\text{kcal/mol)}\,\,\,\,\,\,\text{105}\,\,\,\,\,\,\,\,\,\text{100}\,\,\,\,\,\,\,\,\,\,\,\,\,\text{70} \\ \end{align}\]


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