A) coordination isomers
B) linkage isomers
C) stereoisomers
D) ionisation isomers
Correct Answer: D
Solution :
The complexes\[{{[Co{{(N{{H}_{3}})}_{5}}Br]}^{2+}}SO_{4}^{2-}\]and \[{{[Co{{(N{{H}_{3}})}_{5}}S{{O}_{4}}]}^{+}}B{{r}^{-}}\]are ionization isomers. These can be distinguished by adding \[\text{BaC}{{\text{l}}_{\text{2}}}\]solution to the 1st complex which will give white ppt of\[\text{BaS}{{\text{O}}_{\text{4}}}\]and\[\text{AgN}{{\text{O}}_{\text{3}}}\]solution to 2nd complex which gives pale yellow ppt of AgBr.You need to login to perform this action.
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