J & K CET Engineering J and K - CET Engineering Solved Paper-2013

  • question_answer
    The bond order of\[\text{N}_{\text{2}}^{\text{+}}\]on the basis of molecular orbital theory is [Atomic number of\[\text{N}\,\text{=}\,\text{7}\]]

    A)  3       

    B)  2.5     

    C)  2       

    D)  1.5

    Correct Answer: B

    Solution :

     We know that N3 molecule is having 14 electrons so. \[{{\text{N}}_{\text{2}}}\text{=14}\] \[N_{2}^{+}=14-1=13,\]according to MOT (Molecular orbital theory) the configruation will be \[N_{2}^{+}=KK\,\sigma 2{{S}^{2}}\,{{\sigma }^{*}}2{{S}^{2}}\,\pi 2p_{x}^{2}\,\pi 2p_{y}^{2}\,\sigma 2p_{z}^{1}\] Bond order \[=\frac{1}{2}\] [Bonding - Antibonding] \[=\frac{1}{2}[7-2]\] \[=2\frac{1}{2}=2.5\]


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