J & K CET Medical J & K - CET Medical Solved Paper-2000

  • question_answer
    Vinyl alcohol and acetaldehyde are:

    A)  chain isomers

    B)  keto-enol tautomers

    C)  geometrical isomers

    D)  position isomers

    Correct Answer: B

    Solution :

                    Isomers differ in the arangement of atoms but exist in dynamic equilibrium with each other shows the tautomerism. Acetaldehyde and vinyl alcohol are keto-enol tautomers. \[\underset{\begin{smallmatrix}  acetaldehyde \\  \,\,(keto\text{ }form) \end{smallmatrix}}{\mathop{C{{H}_{3}}-\overset{\begin{smallmatrix}  O \\  || \end{smallmatrix}}{\mathop{C}}\,-H}}\,\underset{\begin{smallmatrix}  vinyl\text{ }alcohol \\  \,(enol\text{ }form) \end{smallmatrix}}{\mathop{C{{H}_{2}}=\overset{\begin{smallmatrix}  OH \\  || \end{smallmatrix}}{\mathop{C}}\,-H}}\,\]


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