J & K CET Medical J & K - CET Medical Solved Paper-2001

  • question_answer
    The difference in activity: \[M{{e}_{2}}CC{{H}_{2}}COOH>M{{e}_{3}}SiC{{H}_{2}}COOH\]can be attributed to the fact diat:

    A)  silicon is more electropositive than carbon and therefore has an electron donating inductive effect

    B)  silicon is a non-metal

    C)  carbon is more electropositive than silicon and has an electron donating inductive effect

    D)  carbon is a non-metal

    Correct Answer: A

    Solution :

                    The reactivity of carboxylic acid depends upon the releasing of H+ ion. Due to the presence of\[+I\]group acidic strength decrease. Hence, reactivity also decreases.\[M{{e}_{3}}C-C{{H}_{2}}COOH\] is more reactive than\[M{{e}_{3}}SiC{{H}_{2}}-COOH\] because Si is more electropositive than carbon. Hence,\[+I\] effect of Si is more than carbon.


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