J & K CET Medical J & K - CET Medical Solved Paper-2001

  • question_answer
    For the reversible system: \[X(g)Y(g)+Z(g),\]a quantity of X was heated at constant pressure P at a certain temperature. The equilibrium partial pressure of X was found to be\[\frac{P}{7}\]. What is the value of \[{{K}_{p}}\]at given temperature?

    A)  \[\frac{6P}{7}\]                               

    B)  \[\frac{9P}{7}\]

    C)  \[\frac{36P}{7}\]                             

    D)  \[6P\]

    Correct Answer: B

    Solution :

                    \[\underset{\begin{smallmatrix}  \,\,\,a \\  a-x \end{smallmatrix}}{\mathop{X}}\,\underset{\begin{smallmatrix}  a \\  x \end{smallmatrix}}{\mathop{Y}}\,+\underset{\begin{smallmatrix}  a \\  x \end{smallmatrix}}{\mathop{Z}}\,\] \[\therefore \]  \[P_{x}^{}=P\frac{(a-x)}{(a+x)}=\frac{P}{7}\] \[\therefore \]  \[7a-7x=a+x\]                 \[6a=8x\]                 \[x=\frac{6a}{8}=\frac{3a}{4}\]                 \[{{K}_{p}}=\frac{{{x}^{2}}}{(a-x)}.\frac{[P]}{[a+x]}\]                 \[=\frac{{{\left( \frac{3a}{4} \right)}^{4}}[P]}{\left( a-\frac{3a}{4} \right)\left( a+\frac{3a}{4} \right)}\]                 \[=\frac{9{{a}^{2}}\times 4\times 4\times P}{16\times a\times 7a}\]                 \[{{K}_{p}}=\frac{9P}{7}\]


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