J & K CET Medical J & K - CET Medical Solved Paper-2002

  • question_answer
    Which one of the following can be converted to\[C{{H}_{3}}CH=CHCHO\]?

    A)  Acetone

    B)  Acetaldehyde

    C)  Propanaldehyde

    D)  Formaldehyde

    Correct Answer: B

    Solution :

                    Acetaldehyde undergoes aldol condensation to form aldol which gives\[C{{H}_{3}}CH=CHCHO\]on heating. \[\underset{acetaldehyde}{\mathop{C{{H}_{3}}CHO}}\,+H.\overset{\alpha }{\mathop{C{{H}_{2}}}}\,CHO\] \[\xrightarrow[NaOH]{dil.}\underset{aldol}{\mathop{C{{H}_{3}}-\underset{\begin{smallmatrix}  | \\  OH \end{smallmatrix}}{\mathop{CH}}\,-C{{H}_{2}}CHO}}\,\]\[\xrightarrow[-{{H}_{2}}O]{{{H}^{+}}\phi }\underset{crotonaldehyde}{\mathop{C{{H}_{3}}CH=CH-CHO}}\,\]


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