J & K CET Medical J & K - CET Medical Solved Paper-2003

  • question_answer
    Which of the following. organic compounds exhibit acidic character?

    A)  \[{{H}_{3}}C-C\equiv CH\]          

    B) \[{{H}_{3}}C-C\equiv C-C{{H}_{3}}\]

    C)  \[{{H}_{2}}C=C{{H}_{2}}\]           

    D)  \[{{H}_{3}}C-C{{H}_{3}}\]

    Correct Answer: A

    Solution :

                    The\[H\]atoms of terminal alkyne (i.e., \[{{H}_{3}}-C\equiv CH)\]is weakly acidic. \[CH\equiv CH+NaN{{H}_{2}}\xrightarrow{liq.\text{ }N{{H}_{3}}}CH\equiv CNa+N{{H}_{3}}\]


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