J & K CET Medical J & K - CET Medical Solved Paper-2003

  • question_answer
    The enthalpy of vaporisation of liquid water using the data: \[{{H}_{2}}(g)+\frac{1}{2}{{O}_{2}}(g)\xrightarrow[{}]{{}}{{H}_{2}}O(l);\]\[\Delta H=-285.77\text{ }kJ/mol\] \[{{H}_{2}}(g)+\frac{1}{2}{{O}_{2}}(g)\xrightarrow[{}]{{}}{{H}_{2}}O(g);\]\[\Delta H=-241.84\text{ }kJ/mol\]is:

    A)  \[+\,43.93kJ/mol\]

    B)  \[-\,43.93\text{ }kJ/mol\]

    C)  \[527.61\text{ }kJ/mol\]

    D)  \[-\,527.61\text{ }kJ/mol\]

    Correct Answer: A

    Solution :

                    (I) \[{{H}_{2}}(g)+\frac{1}{2}{{O}_{2}}(g)\xrightarrow{{}}{{H}_{2}}O(l);\]      \[\Delta H=-285.77\text{ }kJ/mol\] (II) \[{{H}_{2}}(g)+\frac{1}{2}{{O}_{2}}(g)\xrightarrow{{}}{{H}_{2}}O(l);\] \[\Delta H=-241.84kJ/mol\]       \[{{H}_{2}}O(l)\xrightarrow{{}}{{H}_{2}}O(g);\]            \[\Delta H=?\] Subtract the Eq. (I) from (II)                 \[{{H}_{2}}O(l)\xrightarrow[{}]{{}}{{H}_{2}}O(g)\] \[\Delta H=-241.84-(-285.77)\] \[=-241.84+285.77\] \[\Delta H=+43.93\text{ }kJ/mol\]


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