J & K CET Medical J & K - CET Medical Solved Paper-2008

  • question_answer
    Hydroxamic acid test is employed to detect

    A)  ketones                             

    B)  aldehydes

    C)  esters                                 

    D)  amides

    Correct Answer: C

    Solution :

                    Hydroxamic acid test is used to detect the presence of esters. In hydroxamic acid test a few crystals or a few drops of the substance is dissolved in 1 mL of 95% ethanol + 1 mL of \[1\text{ }M\,HCl\]. Then, a drop of 5%\[FeC{{l}_{3}}\]is added. Formation of characteristic colour shows the presence of acyl or ester group. \[R-\overset{\begin{smallmatrix}  O \\  |\,| \end{smallmatrix}}{\mathop{C}}\,-OR+{{H}_{2}}NOH\xrightarrow[{}]{{}}R-\overset{\begin{smallmatrix}  O \\  |\,| \end{smallmatrix}}{\mathop{C}}\,-NHOH\]\[\xrightarrow{FeC{{l}_{3}}}\left( R-\overset{\begin{smallmatrix}  O \\  |\,| \end{smallmatrix}}{\mathop{C}}\,-NOH \right)Fe\]


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