J & K CET Medical J & K - CET Medical Solved Paper-2008

  • question_answer
    When chlorine reacts with dil.\[NaOH\]under cold conditions, the oxidation state of chlorine changes from zero to

    A)  - 1 and + 5         

    B)  + 1 and + 4

    C)  + 5 and + 3        

    D)  - 1 and + 1

    Correct Answer: D

    Solution :

                     When chlorine reacts with dilute and cold\[NaOH,\] sodium chloride and sodium hypochloride are formed. \[2NaOH(cold)+C{{l}_{2}}\to NaCl+\underset{\begin{smallmatrix}  \,\,\,\,\,\,\,sodium \\  hypochloride \end{smallmatrix}}{\mathop{NaClO}}\,+{{H}_{2}}O\] Let oxidation state of\[Cl\]in\[NaClO\]is\[x\]. \[NaCl\] \[+1+x=0\] \[x=-1\] Let oxidation state of\[Cl\]in\[NaClO\]is\[x\]. \[NaClO\] \[+1+x-2=0\]                 \[x-1=0\]                 \[x=+1\] \[\therefore \]Oxidation states of chlorine changes from 0 to- 1 and +1.


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