J & K CET Medical J & K - CET Medical Solved Paper-2011

  • question_answer
    Mendius reaction converts an alkyi cyanide to

    A)  a primary amine             

    B)  an aldehyde

    C)  a ketone            

    D)  an oxime

    Correct Answer: A

    Solution :

                    The reduction of alkyl and aryl cyanides to primary amines with nascent hydrogen is known as Mendius reaction.  \[C{{H}_{3}}CN+4[H]\xrightarrow[{}]{Na/{{C}_{2}}{{H}_{5}}OH}C{{h}_{3}}C{{H}_{2}}N{{H}_{2}}\] \[RCN+4[H]\xrightarrow[{}]{Na/{{C}_{2}}{{H}_{5}}OH}\underset{{{1}^{o}}\,a\min e}{\mathop{RC{{H}_{2}}N{{H}_{2}}}}\,\]


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