J & K CET Medical J & K - CET Medical Solved Paper-2011

  • question_answer
    All Cu (II) halides are known except the iodide. The reason for is that

    A)  iodide is a bulky ion

    B) \[C{{u}^{2+}}\]oxidizes iodide to iodine

    C) \[C{{u}^{2+}}(aq)\]has much more negative hydration enthalpy

    D) \[C{{u}^{2+}}\]ion has smaller size

    Correct Answer: B

    Solution :

                     All Cu (II) halides are known except the iodide because\[C{{u}^{2+}}\]oxidizes iodide to iodine. \[2CuS{{O}_{4}}+4KI\xrightarrow[{}]{{}}2CuI\downarrow +{{I}_{2}}\] \[{{I}_{2}}\]is produced by oxidation of I which reduces\[C{{u}^{2+}}\]to\[CuI\].


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