J & K CET Medical J & K - CET Medical Solved Paper-2014

  • question_answer
    When acetaldehyde is heated with dilute sodium hydroxide solution, the product is

    A)  ethanol and sodium acetate

    B)  paraldehyde

    C)  aldol

    D)  brown resin

    Correct Answer: C

    Solution :

     When two molecules of acetaldehyde are heated with dilute\[NaOH\]solution, aldol is obtained. \[C{{H}_{3}}-\underset{\begin{smallmatrix}  | \\  H \end{smallmatrix}}{\mathop{O}}\,=O+HC{{H}_{2}}-\underset{\begin{smallmatrix}  | \\  H \end{smallmatrix}}{\mathop{C}}\,=O\]\[\xrightarrow[{}]{dill.\,NaOH}C{{H}_{3}}-\underset{\begin{smallmatrix}  | \\  H \end{smallmatrix}}{\mathop{\overset{\begin{smallmatrix}  OH \\  | \end{smallmatrix}}{\mathop{C}}\,}}\,=C{{H}_{2}}-\underset{\begin{smallmatrix}  | \\  H \end{smallmatrix}}{\mathop{C}}\,=O\]


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