A) \[{{K}_{p}}(RT)\]
B) \[{{K}_{p}}/RT\]
C) \[={{K}_{p}}\]
D) \[{{\left( \text{C}{{\text{H}}_{\text{3}}} \right)}_{\text{2}}}\text{NH}>{{\left( \text{C}{{\text{H}}_{\text{3}}} \right)}_{\text{3}}}\text{N}>\text{C}{{\text{H}}_{\text{3}}}\text{N}{{\text{H}}_{\text{2}}}\]
Correct Answer: D
Solution :
Chloroform and acetone form a non-ideal solution, in which A ... B type interaction are more than A...A and B...B type interactions due to H-bonding. Hence, the solution shows negative deviation from Raoulf slaw. i.e., \[\Delta {{V}_{mix}}=-ve\] \[\Delta {{H}_{mix}}=-ve\] \[\therefore \] total volume of solution = less than \[\left( \text{3}0\text{ }+\text{ 5}0 \right)\text{ ml}\] Or \[<\text{8}0\text{ml}\]
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