JAMIA MILLIA ISLAMIA Jamia Millia Islamia Solved Paper-2007

  • question_answer
        The rate equation for the reaction\[2A+B\to C\] is found to be rate\[=k[A]\,[B]\] The correct statement in relation to this reaction is that the

    A)  unit of k must be \[{{s}^{-1}}\]

    B)  \[{{t}_{1/2}}\]is a constant

    C)  rate of formation of C is twice the rate of, disappearance of A

    D)  value of k is independent of the initial concentrations of A and B

    Correct Answer: C

    Solution :

                    \[2A+B\xrightarrow[{}]{{}}C\] Rate\[=k[A][B]\] It represents second-order reaction. Thus unit of k is \[{{M}^{-1}}{{s}^{-1}}\] \[\therefore \]  is false \[{{T}_{50}}\]is dependent of concentration but not constant \[\therefore \](a)  is false \[-\frac{1}{2}\frac{d[A]}{dt}=\frac{d[C]}{dt},\] thus (c) is correct


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