JAMIA MILLIA ISLAMIA Jamia Millia Islamia Solved Paper-2015

  • question_answer
    Which of the following carbocations is most stable?

    A) \[\frac{\pi }{2}\]        

    B) \[C{{H}_{2}}=\overset{+}{\mathop{C}}\,H\]

    C) \[CH\equiv \overset{+}{\mathop{C}}\,\]             

    D) \[\text{5a}+\text{2b}\]

    Correct Answer: A

    Solution :

    Greater the delocalisation of positive charge by hyper conjugation of alkyl carbocation, higher is the stability. Hence, the order of stability of alkyl carbocations is\[\text{3}.\text{75}\times \text{1}{{0}^{\text{5}}}\] The. electronegativity of carbon increases with increases in s-character of hybrid orbitals which result decreases the stability of carbocation.                


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