JEE Main & Advanced JEE Main Solved Paper-2016

  • question_answer
    2-chloro-2-methylpentane on reaction with sodium methoxide in methanol yields : [JEE Main Solved Paper-2016 ]
     (a)   \[{{C}_{2}}{{H}_{5}}C{{H}_{2}}\underset{\begin{smallmatrix}  | \\  C{{H}_{3}} \end{smallmatrix}}{\overset{\begin{smallmatrix}  C{{H}_{3}} \\  | \end{smallmatrix}}{\mathop{C}}}\,-OC{{H}_{3}}\]
     (b)   \[{{C}_{2}}{{H}_{5}}C{{H}_{2}}\underset{\begin{smallmatrix}  | \\  C{{H}_{3}} \end{smallmatrix}}{\mathop{C}}\,=C{{H}_{2}}\]
     (c)   \[{{C}_{2}}{{H}_{5}}C{{H}_{2}}=\underset{\begin{smallmatrix}  | \\  C{{H}_{3}} \end{smallmatrix}}{\mathop{C}}\,-C{{H}_{3}}\]
     

    A) (a) and (b)                

    B) All of these

    C) (a) and (c)                 

    D) (c) only

    Correct Answer: B

    Solution :

    \[{{C}_{2}}{{H}_{5}}C{{H}_{2}}\underset{\begin{smallmatrix}  | \\  Cl \end{smallmatrix}}{\overset{\begin{smallmatrix}  C{{H}_{3}} \\  | \end{smallmatrix}}{\mathop{C}}}\,-C{{H}_{3}}\xrightarrow[C{{H}_{3}}OH]{NaOC{{H}_{3}}}\] possible mechanism which takes place is \[{{E}^{2}}\And S{{N}^{1}}\]mechanism. Hence possible products are. \[{{C}_{2}}{{H}_{5}}C{{H}_{2}}\underset{\begin{smallmatrix}  | \\  C{{H}_{3}}  \\  (S{{N}^{1}}) \end{smallmatrix}}{\overset{\begin{smallmatrix}  C{{H}_{3}} \\  | \end{smallmatrix}}{\mathop{C}}}\,-OC{{H}_{3}}\]\[\underbrace{\begin{matrix}    {{C}_{2}}{{H}_{5}}C{{H}_{2}}\underset{\begin{smallmatrix}  | \\  C{{H}_{3}} \end{smallmatrix}}{\mathop{C}}\,=C{{H}_{2}} & {{C}_{2}}{{H}_{5}}CH=\underset{\begin{smallmatrix}  | \\  C{{H}_{3}} \end{smallmatrix}}{\mathop{C}}\,-C{{H}_{3}}  \\ \end{matrix}}_{({{E}^{2}})}\]


You need to login to perform this action.
You will be redirected in 3 sec spinner