JIPMER Jipmer Medical Solved Paper-1995

  • question_answer
    Which of the following complex will give white precipitate with\[BaC{{l}_{2}}(aq.)\]?

    A)  \[[Co{{(N{{H}_{3}})}_{4}}S{{O}_{4}}]N{{O}_{2}}\]

    B)  \[[Cr{{(N{{H}_{3}})}_{5}}S{{O}_{4}}]Cl\]

    C)  \[[Cr{{(N{{H}_{3}})}_{5}}Cl]S{{O}_{4}}\]

    D)  both (b) and (c)

    Correct Answer: C

    Solution :

    Only \[[Cr{{(N{{H}_{3}})}_{5}}Cl]\,S{{O}_{4}}\] give sulphate ions\[(SO_{4}^{2-})\] in solution, hence only it will give white precipitate of barium sulphate with\[BaC{{l}_{2}}(aq).\] \[[Cr{{(N{{H}_{3}})}_{5}}Cl]\,S{{O}_{4}}+BaC{{l}_{2}}\xrightarrow{{}}\] \[[Cr{{(N{{H}_{3}})}_{5}}Cl]\,C{{l}_{2}}+\underset{\text{White}}{\mathop{BaS{{O}_{4}}\downarrow }}\,\]


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