JIPMER Jipmer Medical Solved Paper-1996

  • question_answer
    Which of the following quantities are equal at equilibrium under the particular set of conditions?

    A)  \[\Delta H\] and \[\Delta G\]                    

    B)  \[\Delta H\] and \[\Delta S\]

    C)         \[\Delta G\] and \[\Delta S\]     

    D)         none of these

    Correct Answer: D

    Solution :

    At equilibrium state, \[\Delta G=0\] Hence, from Gibbs-Helmholtz equation, \[\Delta G=\Delta H-T\cdot \Delta S\] \[0=\Delta H-T\cdot \Delta S\] \[\therefore \]  \[\Delta H=T\cdot \Delta S\]


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