JIPMER Jipmer Medical Solved Paper-2000

  • question_answer
    What is the end product in the following reaction? \[{{C}_{2}}{{H}_{5}}N{{H}_{2}}\xrightarrow{HN{{O}_{2}}}A\xrightarrow{PC{{l}_{5}}}B\xrightarrow{N{{H}_{3}}}C\]

    A)  Methyl amine                  

    B)  Acetamide        

    C)         Ethyl cyanide  

    D)         Ethyl amine

    Correct Answer: D

    Solution :

    The reactions occur in the following way \[{{C}_{2}}{{H}_{5}}N{{H}_{2}}\xrightarrow[-{{N}_{2}}]{HN{{O}_{2}}}\underset{\text{(A)}}{\mathop{{{C}_{2}}{{H}_{5}}OH}}\,\xrightarrow{PC{{l}_{5}}}\] \[\underset{(B)}{\mathop{{{C}_{2}}{{H}_{5}}Cl}}\,\xrightarrow{N{{H}_{3}}}\,\underset{(C)\,\,Ethyl\,\,a\min e}{\mathop{{{C}_{2}}{{H}_{5}}N{{H}_{2}}}}\,\] Thus, ethyl amine is obtained back.


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