JIPMER Jipmer Medical Solved Paper-2000

  • question_answer
    On heating \[NaCl+{{K}_{2}}C{{r}_{2}}{{O}_{7}}+\] cone. \[{{H}_{2}}S{{O}_{4}},\] the gas comes out is:

    A)  \[{{O}_{2}}\]        

    B)                         \[C{{l}_{2}}\]                    

    C)  \[CrOC{{l}_{2}}\]        

    D)         \[Cr{{O}_{2}}C{{l}_{2}}\]

    Correct Answer: D

    Solution :

    This reaction is used to confirm the presence of \[C{{l}^{-}}\] ion in a mixture. In this, orange-red vapours of chrornyl chloride obtained on heating the reaction mixture. \[4NaCl+{{K}_{2}}C{{r}_{2}}{{O}_{7}}+6{{H}_{2}}S{{O}_{4}}\xrightarrow{\Delta }2KHS{{O}_{4}}\] \[+\,4NaHS{{O}_{4}}+\underset{\text{Orange-red}}{\mathop{2Cr{{O}_{2}}C{{l}_{2}}\uparrow }}\,+3{{H}_{2}}O\]


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