JIPMER Jipmer Medical Solved Paper-2010

  • question_answer
    The complex ion which has no d-electrons in the central metal atom is

    A)  \[{{[Mn{{O}_{4}}]}^{-}}\]            

    B)         \[{{[Co{{(N{{H}_{3}})}_{6}}]}^{3+}}\]

    C)                         \[{{[Fe{{(CN)}_{6}}]}^{3-}}\]     

    D)         \[{{[Cr{{({{H}_{2}}O)}_{6}}]}^{3+}}\]

    Correct Answer: A

    Solution :

    In \[{{[Mn{{O}_{4}}]}^{-}},\]the oxidation state of Mn is +7. \[Mn\,(25)=[Ar]\,3{{d}^{5}}4{{s}^{2}}\] \[M{{n}^{7+}}=[Ar]\] Thus, in \[{{[Mn{{O}_{4}}]}^{-}}\] no d-electron is present.


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