JIPMER Jipmer Medical Solved Paper-2010

  • question_answer
    The solubility of saturated solution of \[A{{g}_{2}}Cr{{O}_{4}}\]\[s\,mol\,{{L}^{-1}}\]. What is its solubility product?

    A)  \[4{{s}^{3}}\]                   

    B)         \[{{s}^{3}}\]                      

    C)  \[2{{s}^{3}}\]                   

    D)         \[16{{s}^{2}}\]

    Correct Answer: A

    Solution :

    \[A{{g}_{2}}Cr{{O}_{4}}\]ionises completely in the solution as \[\underset{s\,\,mol\text{/}L}{\mathop{A{{g}_{2}}Cr{{O}_{4}}}}\,\xrightarrow{{}}\underset{2s\,\,mol\text{/}L}{\mathop{2A{{g}^{+}}}}\,+\underset{s\,\,mol\text{/}L}{\mathop{CrO_{4}^{2-}}}\,\] Hence, the solubility product, \[{{K}_{sp}}\]of\[A{{g}_{2}}Cr{{O}_{4}}={{[A{{g}^{+}}]}^{2}}[CrO_{4}^{2-}]\] \[={{(2s)}^{2}}(s)\] \[=4{{s}^{3}}\]


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