JIPMER Jipmer Medical Solved Paper-2013

  • question_answer
    \[\frac{3}{2}{{O}_{2}}(g)\to {{O}_{3}}(g);\]\[{{K}_{p}}\] for this reaction is \[2.47\times {{10}^{-29}}.\] At 298 K, \[{{\Delta }_{r}}G{}^\circ \]for conversation of oxygen to ozone will be

    A)  \[100\text{ }kJ\,mo{{l}^{-1}}\]                 

    B)  \[150\text{ }kJ\,mo{{l}^{-1}}\]

    C)  \[163\text{ }kJ\,mo{{l}^{-1}}\]   

    D)         \[2303\text{ }kJ\,mo{{l}^{-1}}\]

    Correct Answer: C

    Solution :

      \[{{\Delta }_{r}}G{}^\circ =2.303\,\,\log {{K}_{p}}(R=8.314\,J{{K}^{-1}}mo{{l}^{-1}})\] \[{{\Delta }_{r}}G{}^\circ =-\,2.303\times 8.314\,J{{K}^{-1}}mo{{l}^{-1}}\times 298\,K\]                                        \[\times \log 2.47\times {{10}^{-29}}\] \[=163000\text{ }J\,mo{{l}^{-1}}=163\text{ }kJ\,mo{{l}^{-1}}\]


You need to login to perform this action.
You will be redirected in 3 sec spinner